UPSC Prelims 2024 Q37: Science & Technology – Energy
Which one of the following is the exhaust pipe emission from Fuel Cell Electric Vehicles,
powered by hydrogen ?
- (a) Hydrogen peroxide
- (b) Hydronium
- (c) Oxygen
- (d) Water vapour
Answer: (d) Water vapour
Explanation
Fuel Cell Electric Vehicles (FCEVs) — what comes out of the exhaust?
| Part of the reaction | What happens |
|---|---|
| Anode | Hydrogen (H₂) splits into protons (H⁺) and electrons |
| Electrolyte | Only protons pass through (in PEM fuel cells) |
| External circuit | Electrons flow and power the motor |
| Cathode | Protons, electrons and oxygen from air combine to form water |
Overall reaction: 2H₂ + O₂ → 2H₂O + electricity + heat
The only tailpipe output is water vapour, so FCEVs have zero tailpipe emissions.
FCEV vs battery EV:
| Feature | FCEV | Battery EV |
|---|---|---|
| Energy store | Hydrogen tank | Lithium-ion battery |
| Refuel time | About 5 minutes | 30 minutes to several hours |
| Exhaust | Water vapour | None |
Answer: (d) Water vapour.
Why each option is right or wrong
- (a) Incorrect. Hydrogen peroxide is not formed in a fuel cell's normal reaction.
- (b) Incorrect. Hydronium (H₃O⁺) ions exist in solution; they are not released as exhaust.
- (c) Incorrect. Oxygen is taken in from air at the cathode, not given out.
- (d) CORRECT. Hydrogen combines with oxygen to form water vapour, the only exhaust.
Key point
Hydrogen fuel cell: 2H₂ + O₂ → 2H₂O + electricity. The only exhaust is water vapour.
Remember
A hydrogen fuel cell car emits only water vapour.
Common mistakes
- Thinking the vehicle releases oxygen; it actually consumes oxygen from the air.
- Assuming FCEVs burn hydrogen like petrol; it is an electrochemical reaction, not combustion.
- Forgetting that 'green' depends on how the hydrogen was made — green hydrogen uses renewable electricity.
Exam tip
Hydrogen + oxygen always give water. Any option other than water is wrong for an FCEV exhaust.
Sources
- Ministry of New and Renewable Energy — National Green Hydrogen Mission (2023)
- NCERT Class XII — Chemistry, Ch 2 (Electrochemistry — Fuel cells)