UPSC Prelims 2009 Q65: Science & Technology – Energy & Environment
In a dry cell (battery),
which of the following are used as electrolytes?
- (a) Ammonium chloride and Zinc chloride
- (b) Sodium chloride and Calcium chloride
- (c) Magnesium chloride and Zinc chloride
- (d) Ammonium chloride and Calcium chloride
Answer: (a) Ammonium chloride and Zinc chloride
Explanation
Electrolytes used in a dry cell battery
A standard dry cell relies on specific chemical compounds to function as its electrolyte.
| Option | Verdict | Reason |
|---|---|---|
| (a) Ammonium chloride and Zinc chloride | Correct | A typical dry cell uses a paste of ammonium chloride and zinc chloride as its electrolyte |
| (b) Sodium chloride and Calcium chloride | Incorrect | These are not the standard dry cell electrolytes |
| (c) Magnesium chloride and Zinc chloride | Incorrect | Magnesium chloride is not part of the standard dry cell formulation |
| (d) Ammonium chloride and Calcium chloride | Incorrect | Calcium chloride is not the correct pairing here |
Dry cell electrolyte facts:
| Point | Detail |
|---|---|
| Electrolyte paste | Ammonium chloride + Zinc chloride |
| Cell type | Leclanché dry cell |
Answer: (a) Ammonium chloride and Zinc chloride.
Why each option is right or wrong
- (a) CORRECT. Ammonium chloride and zinc chloride form the standard dry cell electrolyte paste.
- (b) Incorrect. Sodium chloride and calcium chloride are not this electrolyte's components.
- (c) Incorrect. Magnesium chloride is not part of the standard formulation.
- (d) Incorrect. Calcium chloride is not the correct pairing.
Key point
A standard dry cell uses a paste of AMMONIUM CHLORIDE and ZINC CHLORIDE as its electrolyte.
Remember
Dry cell batteries use ammonium chloride and zinc chloride as the electrolyte.
Common mistakes
- Confusing the dry cell's actual electrolyte (ammonium + zinc chloride) with other chloride compounds.
- Not knowing the specific Leclanché cell chemistry behind common dry cell batteries.
- Mixing up different battery chemistries' specific electrolyte formulations.
Exam tip
Dry cell (Leclanché) electrolyte = ammonium chloride + zinc chloride. A specific battery-chemistry fact.
Sources
- NCERT Class XII Chemistry — Electrochemistry (batteries: the dry cell)
- Encyclopaedia Britannica — dry cell